Synthesis of Benzylic Alcohols by C–H Oxidation
نویسندگان
چکیده
منابع مشابه
Oxidation of benzylic alcohols with molecular oxygen catalyzed by Cu3/2[PMo12O40]/SiO2
The aerobic oxidation of alcohols was efficiently completed in high conversion and selectivity using Cu3/2[PMo12O40]/SiO2 as catalyst under mild reaction condition. This reaction provides a new environmentally friendly rout to the conversion of alcoholic function to carbonyl groups.
متن کاملOxidation of benzylic alcohols with molecular oxygen catalyzed by Cu3/2[PMo12O40]/SiO2
The aerobic oxidation of alcohols was efficiently completed in high conversion and selectivity using Cu3/2[PMo12O40]/SiO2 as catalyst under mild reaction condition. This reaction provides a new environmentally friendly rout to the conversion of alcoholic function to carbonyl groups.
متن کاملSynthesis and Comparative Catalytic Study of Zirconia–MnCO3 or –Mn2O3 for the Oxidation of Benzylic Alcohols
We report on the synthesis of the zirconia-manganese carbonate ZrOx(x %)-MnCO3 catalyst (where x=1-7) that, upon calcination at 500 °C, is converted to zirconia-manganese oxide ZrOx(x %)-Mn2O3 . We also present a comparative study of the catalytic performance of the both catalysts for the oxidation of benzylic alcohol to corresponding aldehydes by using molecular oxygen as the oxidizing age...
متن کاملShape-Selective Oxidation of Benzylic Alcohols by a Receptor Functionalized with a Dicopper(II) Pyrazole Complex
A novel metallohost containing a substrate-binding site and two copper ions held by two bis-pyrazole ligand sets is described. The cavity of this molecule can bind dihydroxybenzene guests (association constants in chloroform are in the range K& = 2000-3000 M-1). In the presence of benzylic alcohols the Cu(II) centers of the metallohost are reduced to Cu(I). During this process the alcohols are ...
متن کاملoxidation of benzylic alcohols with molecular oxygen catalyzed by cu3/2[pmo12o40]/sio2
the aerobic oxidation of alcohols was efficiently completed in high conversion and selectivity using cu3/2[pmo12o40]/sio2 as catalyst under mild reaction condition. this reaction provides a new environmentally friendly rout to the conversion of alcoholic function to carbonyl groups.
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ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 2019
ISSN: 0002-7863,1520-5126
DOI: 10.1021/jacs.9b09496